An unprecedented ten-connected 3D metal-organic framework based on hexanuclear cobalt(II) cluster building blocks

被引：9
|
作者：
Guo, Zhiyong [1 ]
Su, Shengqun [1 ]
Deng, Ruiping [1 ]
Zhang, Hongjie [1 ]
机构：
[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2015年 / 51卷
基金：
中国国家自然科学基金;
关键词：
Metal-organic framework; Biphenyl-3; 4'; 5-tricarboxylate; (H3BPT); Crystal structure; Free carboxylic acids; Antiferromagnetic interaction; MAGNETIC-PROPERTIES; PENTANUCLEAR; RELAXATION; NETWORK; BINDING; LIGAND; UNITS;
D O I：
10.1016/j.inoche.2014.10.030
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 3D metal-organic framework (MOF), [Co-3(mu(3)-OH)(mu(2)-H2O)(BPT)(HBPT)(DMF)(2)] (DMF)(H2O) (1) (DMF = N, N'-dimethylformamide) has been synthesized by self-assembly of cobalt(II) oxide and biphenyl-3, 4', 5-tricarboxylate (H3BPT) under solvothermal reaction. Compound 1 displays unique (2,3,10)-connected trinodal connected topology. Besides, 1 represents a rare example of MOF possessing free carboxylic acids. In addition, the magnetic property of the compound is investigated. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：9 / 12
页数：4
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