Synthesis and thermal stability of imino-1,3-dithietanes. Influence of structural factors

被引：6
|
作者：
Ogurtsov, V. A. [1 ]
Karpychev, Yu. V. [1 ]
Belyakov, P. A. [1 ]
Nelyubina, Yu. V. [2 ]
Lyssenko, K. A. [2 ]
Rakitin, O. A. [1 ]
机构：
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 02期
关键词：
1,3-dithietanes; 1,2-dithiol-3-thiones; isonitriles; equilibrium; H-1 NMR spectroscopy; X-ray diffraction study; RING-SYSTEM; DERIVATIVES; ISOCYANIDES; CHLORIDE; ESTERS; THIONO; DIMER;
D O I：
10.1007/s11172-010-0028-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of 1,2-dithiol-3-thiones with isonitriles at room temperature affords imino-1,3-dithietanes. The reaction is reversible. According to H-1 NMR spectroscopy, the rise of the temperature shifts the equilibrium to the starting compounds. The structure of one of the imino-1,3-dithietanes was established by X-ray diffraction.
引用
收藏
页码：430 / 436
页数：7
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