Synthesis and thermal stability of imino-1,3-dithietanes. Influence of structural factors

被引：6

作者：

Ogurtsov, V. A. ^{[1
]}

Karpychev, Yu. V. ^{[1
]}

Belyakov, P. A. ^{[1
]}

Nelyubina, Yu. V. ^{[2
]}

Lyssenko, K. A. ^{[2
]}

Rakitin, O. A. ^{[1
]}

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2009年 / 58卷 / 02期

关键词：

1,3-dithietanes; 1,2-dithiol-3-thiones; isonitriles; equilibrium; H-1 NMR spectroscopy; X-ray diffraction study; RING-SYSTEM; DERIVATIVES; ISOCYANIDES; CHLORIDE; ESTERS; THIONO; DIMER;

D O I：

10.1007/s11172-010-0028-0

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of 1,2-dithiol-3-thiones with isonitriles at room temperature affords imino-1,3-dithietanes. The reaction is reversible. According to H-1 NMR spectroscopy, the rise of the temperature shifts the equilibrium to the starting compounds. The structure of one of the imino-1,3-dithietanes was established by X-ray diffraction.

引用

页码：430 / 436

页数：7

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