Azido{2-[2-(piperidin-1-yl)ethylimino-methyl]1-naphtholato}nickel(II)

被引:5
|
作者
Zhou, Zhi [1 ]
Xiao, Zun-Hong
机构
[1] Kaili Coll, Dept Chem, Guizhou 556000, Peoples R China
[2] Guizhou Normal Univ, Coll Chem & Phys, Guiyang 550001, Peoples R China
关键词
D O I
10.1107/S1600536807030930
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [ Ni( C18H21N2O)( N-3)], was obtained by the reaction of the Schiff base ligand 2-[2-( piperidin-1yl) ethyliminomethyl]-1-naphthol with sodium azide and nickel( II) nitrate in methanol solution. The Ni atom is four-coordinated by the N, N, O-donor set of the Schiff base ligand and by the terminal N atom of the azide group, forming a square-planar geometry. The piperidine ring adopts a chair conformation and lies nearly perpendicular to the naphthalene system.
引用
收藏
页码:M2012 / U2009
页数:8
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