Sequential Molecular Conjugation Using Thiophene S,S-Dioxides Bearing a Clickable Functional Group

被引：20

作者：

Meguro, Tomohiro ^{[1
]}

Yoshida, Suguru ^{[1
]}

Hosoya, Takamitsu ^{[1
]}

机构：

[1] Tokyo Med & Dent Univ, Lab Chem Biosci, Inst Biomat & Bioengn, Chiyoda Ku, 2-3-10 Kanda Surugadai, Tokyo 1010062, Japan

来源：

CHEMISTRY LETTERS | 2017年 / 46卷 / 08期

关键词：

Thiophene S; S-dioxide; Cyclooctyne; Diels-Alder reaction; LIVING CELLS; COPPER-FREE; CYCLOADDITIONS; CHEMISTRY; 1,1-DIOXIDE; DERIVATIVES; CYCLOOCTYNES; REACTIVITY; PRODRUGS; BIOLOGY;

D O I：

10.1246/cl.170426

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electron-deficient thiophene dioxides have been found to react rapidly with a bicyclo[6.1.0]non-4-yne derivative to afford benzocyclooctenes in excellent yields. Thiophene dioxides bearing a clickable functional group served as efficient bisreactive platform molecules that enabled sequential molecular conjugation in a simple operation.

引用

页码：1137 / 1140

页数：4

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