Sequential Molecular Conjugation Using Thiophene S,S-Dioxides Bearing a Clickable Functional Group

被引：20
|
作者：
Meguro, Tomohiro [1 ]
Yoshida, Suguru [1 ]
Hosoya, Takamitsu [1 ]
机构：
[1] Tokyo Med & Dent Univ, Lab Chem Biosci, Inst Biomat & Bioengn, Chiyoda Ku, 2-3-10 Kanda Surugadai, Tokyo 1010062, Japan
来源：
CHEMISTRY LETTERS | 2017年 / 46卷 / 08期
关键词：
Thiophene S; S-dioxide; Cyclooctyne; Diels-Alder reaction; LIVING CELLS; COPPER-FREE; CYCLOADDITIONS; CHEMISTRY; 1,1-DIOXIDE; DERIVATIVES; CYCLOOCTYNES; REACTIVITY; PRODRUGS; BIOLOGY;
D O I：
10.1246/cl.170426
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electron-deficient thiophene dioxides have been found to react rapidly with a bicyclo[6.1.0]non-4-yne derivative to afford benzocyclooctenes in excellent yields. Thiophene dioxides bearing a clickable functional group served as efficient bisreactive platform molecules that enabled sequential molecular conjugation in a simple operation.
引用
收藏
页码：1137 / 1140
页数：4
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