Isotope effects in the far-infrared spectra of histamine complexes with palladium(II)

被引：11
|
作者：
Drozdzewski, P [1 ]
Kordon, E [1 ]
机构：
[1] Wroclaw Tech Univ, Inst Inorgan Chem & Met Rare Elements, PL-50370 Wroclaw, Poland
来源：
VIBRATIONAL SPECTROSCOPY | 2000年 / 24卷 / 02期
关键词：
far-infrared; Raman spectra; isotope effects; histamine-palladium(II) complexes;
D O I：
10.1016/S0924-2031(00)00092-8
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Far-infrared spectra of histamine (hm) complexes [Pd(hm)(2)]Cl-2, and [Pd(hm)Cl-2] have been interpreted based on metal isotope substitution, partial deuteration and halogen exchange. Stretching vibrations of palladium(II)-histamine bonds have been detected at 464 and 372 cm(-1) for Pd-NH2, and at 311 cm(-1) for Pd-N (imidazole), Palladium(II)-halogen modes have been located at 326 and 311cm(-1) for chloro complex and at 205 and 198 cm(-1) for the bromo analogue, respectively. (C) 2000 Elsevier Science B.V, All rights reserved.
引用
收藏
页码：243 / 248
页数：6
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