Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions

被引：24

作者：

Yusubov, Mekhman S. ^{[1
,2
]}

Celik, Cumali ^{[3
,4
]}

Geraskina, Margarita R. ^{[3
]}

Yoshimura, Akira ^{[3
]}

Zhdankin, Viktor V. ^{[3
]}

Nemykin, Victor N. ^{[3
]}

机构：

[1] Tomsk Polytech Univ, Tomsk 634050, Russia

[2] Siberian State Med Univ, Tomsk 634050, Russia

[3] Univ Minnesota, Dept Chem & Biochem, Duluth, MN 55812 USA

[4] Yalova Univ, Yalova Community Coll, TR-77200 Yalova, Turkey

来源：

TETRAHEDRON LETTERS | 2014年 / 55卷 / 41期

基金：

俄罗斯科学基金会; 美国国家科学基金会;

关键词：

Oxygenation; Catalytic oxidation; Phthalocyanines; Tetraazaporphyrin; METALLOPORPHYRIN CATALYSTS; PERIPHERAL SUBSTITUENTS; KEY ROLE; OXIDATION; PHTHALOCYANINES; HYDROCARBONS; IODOSYLBENZENE; VITAMIN-K-3; REACTIVITY; CHEMISTRY;

D O I：

10.1016/j.tetlet.2014.08.070

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin mu-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)(5) and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：5687 / 5690

页数：4

共 26 条

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