Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer: a highly efficient catalyst for biomimetic oxygenation reactions

被引：24
|
作者：
Yusubov, Mekhman S. [1 ,2 ]
Celik, Cumali [3 ,4 ]
Geraskina, Margarita R. [3 ]
Yoshimura, Akira [3 ]
Zhdankin, Viktor V. [3 ]
Nemykin, Victor N. [3 ]
机构：
[1] Tomsk Polytech Univ, Tomsk 634050, Russia
[2] Siberian State Med Univ, Tomsk 634050, Russia
[3] Univ Minnesota, Dept Chem & Biochem, Duluth, MN 55812 USA
[4] Yalova Univ, Yalova Community Coll, TR-77200 Yalova, Turkey
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 41期
基金：
俄罗斯科学基金会; 美国国家科学基金会;
关键词：
Oxygenation; Catalytic oxidation; Phthalocyanines; Tetraazaporphyrin; METALLOPORPHYRIN CATALYSTS; PERIPHERAL SUBSTITUENTS; KEY ROLE; OXIDATION; PHTHALOCYANINES; HYDROCARBONS; IODOSYLBENZENE; VITAMIN-K-3; REACTIVITY; CHEMISTRY;
D O I：
10.1016/j.tetlet.2014.08.070
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin mu-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)(5) and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5687 / 5690
页数：4
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