Selective oxidation of tertiary amines on gold catalysts

被引:31
|
作者
Della Pina, Cristina
Falletta, Ermelinda
Rossi, Michele
机构
[1] Univ Milan, Dipartimento Chim Inorgan & Met Organ, CIMAINA, I-20133 Milan, Italy
[2] Univ Milan, ISTM, I-20133 Milan, Italy
关键词
D O I
10.1007/s11244-007-0306-8
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Gold-based mono-and bi-metallic catalysts have been evaluated in the aerobic oxidation of aqueous solutions of tertiary amines to produce the corresponding N-oxides obtaining 100% yield in the case of triethylamine, pyridine and 3-dimethylaminopropan-1-ol under mild conditions.
引用
收藏
页码:325 / 329
页数:5
相关论文
共 50 条
  • [31] LOCALIZED BASIFICATION OF CATALYTIC SURFACES ENHANCES THE SELECTIVE OXIDATION OF L-SORBOSE OVER SUPPORTED PT CATALYSTS MODIFIED WITH TERTIARY-AMINES
    BRONNIMANN, C
    MALLAT, T
    BAIKER, A
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (13) : 1377 - 1378
  • [32] THE OXIDATION OF PHENOLS WITH COPPER-AMINE CATALYSTS AND ITS RELATION TO THE MODE OF ACTION OF TYROSINASE .2. THE OXIDATION OF NAPHTHOLS WITH TERTIARY AMINES AS CATALYSTS
    BRACKMAN, W
    HAVINGA, E
    RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS-JOURNAL OF THE ROYAL NETHERLANDS CHEMICAL SOCIETY, 1955, 74 (8-9): : 1021 - 1039
  • [33] CATALYSTS OF SELECTIVE OXIDATION
    KRYLOV, OV
    VESTNIK AKADEMII NAUK SSSR, 1983, (01) : 26 - 33
  • [34] Selective oxidation of carbohydrates with gold catalysts:: Continuous-flow reactor system for glucose oxidation
    Thielecke, Nadine
    Ayternir, Mehmet
    Pruesse, Ulf
    CATALYSIS TODAY, 2007, 121 (1-2) : 115 - 120
  • [35] Oxygen-Rich Carbon Quantum Dots as Catalysts for Selective Oxidation of Amines and Alcohols
    Ye, Jianglin
    Ni, Kun
    Liu, Jie
    Chen, Guanxiong
    Ikram, Mujtaba
    Zhu, Yanwu
    CHEMCATCHEM, 2018, 10 (01) : 259 - 265
  • [36] Gold nanoparticles supported on modified silica materials as selective catalysts for oxidation of glucose
    Odrozek, Klaudia
    Maresz, Katarzyna
    Mrowiec-Bialon, Julita
    PRZEMYSL CHEMICZNY, 2012, 91 (09): : 1863 - 1867
  • [37] Ceria supported gold-platinum catalysts for the selective oxidation of alkyl ethoxylates
    Heidkamp, Katharina
    Aytemir, Memet
    Vorlop, Klaus-Dieter
    Pruesse, Ulf
    CATALYSIS SCIENCE & TECHNOLOGY, 2013, 3 (11) : 2984 - 2992
  • [38] Beneficial Interaction of Gold and Palladium in Bimetallic Catalysts for the Selective Oxidation of Benzyl Alcohol
    Marx, Stefan
    Baiker, Alfons
    JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (15): : 6191 - 6201
  • [39] Oxidation of Glycerol by Gold Catalysts
    Bombos, Mihaela
    Bombos, Dorin
    Chivu, Oana Roxana
    Bolocan, Ion
    REVISTA DE CHIMIE, 2015, 66 (09): : 1513 - 1515
  • [40] FORMATION OF LACTAMS BY SELECTIVE OXIDATION OF CYCLIC TERTIARY-AMINES WITH BROMINE UNDER BASIC CONDITIONS
    PICOT, A
    LUSINCHI, X
    SYNTHESIS-STUTTGART, 1975, (02): : 109 - 111