Investigation of interdiffusion in Ba(Ti,Zr)O3-based Y5V multilayer ceramic capacitors with Ni electrodes

被引:0
|
作者
Chen, Lei [1 ]
Wang, Xiaohui [1 ]
Qiao, Bin [1 ]
Li, Longtu [1 ]
机构
[1] Tsinghua Univ, State Key Lab New Ceram & Fine Proc, Dept Mat Sci & Engn, Beijing 100084, Peoples R China
关键词
interdiffusion; Ba(Ti; Zr)O-3; Y5V; MLCCs; capacitor;
D O I
10.1143/JJAP.46.780
中图分类号
O59 [应用物理学];
学科分类号
摘要
The interdiffusion between the Ba(Ti.Zr)O-3 (BTZ) dielectric and the internal Ni electrode layers in Y5V-type multilayer ceramic capacitors (MLCCs) with an active layer thickness of 5 mu m was studied by high-resolution transmission electron microscopy (HRTEM) and energy-dispersive spectrometry (EDS) analysis. It was found that such interdiffusion leads to the formation of some defects and the lattice distortion near the interface. The diffusion degree of Ni into BTZ was higher than that of BTZ into Ni. In the EDS analysis the chemical composition was confirmed and the different diffusion degrees were verified. The generation of the interdiffusion and the relationship between the interdiffusion and degradation of MLCCs with Ni electrodes were also studied.
引用
收藏
页码:780 / 782
页数:3
相关论文
共 50 条
  • [31] Relationship between microstructural evolution and electrical properties in Ba(Ti, Zr)O3-based materials for Ni-MLCC
    Mizuno, Y
    Morita, K
    Hagiwara, T
    Kishi, H
    Ohnuma, K
    Ohsato, H
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2004, 43 (9B): : 6640 - 6644
  • [32] Phase transformation in the synthesis of Ba(Ti1-xMx)O3-based PTCR ceramic
    V'yunov, OI
    Belous, AG
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (6-7) : 935 - 938
  • [33] Phase transformation in the synthesis of Ba(Ti1-xMx)O3-based PTCR ceramic
    Inst of General and Inorganic, Chemistry, Kyiv, Ukraine
    J Eur Ceram Soc, 6-7 (935-938):
  • [34] Effect of Li2O-SiO2-xMO glass addition on the dielectric properties and microstructures of (Ba,Ca)(Ti,Zr)O3 for multilayer ceramic capacitors with nickel electrodes
    Choi, CH
    Chang, DG
    Kim, WS
    Hur, KH
    Choi, CJ
    JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2003, 42 : S1017 - S1020
  • [35] Preparation of (111)-oriented SrRuO3/Pt electrodes for Pb(Zr,Ti)O3-based ferroelectric capacitors:: Grain size and roughness impact
    Menou, Nicolas
    Funakubo, Hiroshi
    JAPANESE JOURNAL OF APPLIED PHYSICS, 2008, 47 (02) : 1003 - 1007
  • [36] Ba(Ce,Zr)O3-based electrodes for protonic ceramic electrochemical cells: towards highly compatible functionality and triple-conducting behaviour
    Kasyanova, Anna V.
    Tarutina, Liana R.
    Rudenko, Anna O.
    Lyagaeva, Julia G.
    Medvedev, Dmitry A.
    RUSSIAN CHEMICAL REVIEWS, 2020, 89 (06) : 667 - 692
  • [37] Investigation of PtNb alloy electrodes for ferroelectric Pb(Zr, Ti)O 3 thin film capacitors
    Kurita, Masaaki
    Okamura, Soichiro
    Shiosaki, Tadashi
    1600, Japan Society of Applied Physics (43):
  • [38] Structural origin of strongly diffused ferroelectric phase transition in Ba(Ti, Zr)O3-based ceramics
    Talanov, Mikhail, V
    Bush, Alexander A.
    Sirotinkin, Vladimir P.
    Kozlov, Vladislav, I
    ACTA MATERIALIA, 2022, 227
  • [39] Effect of the A/B ratio on the microstructures and electrical properties of (Ba0.95±xCa0.05)(Ti0.82Zr0.18)O3 for multilayer ceramic capacitors with nickel electrodes
    Jain, T. A.
    Fung, K. Z.
    Chan, Johnny
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 468 (1-2) : 370 - 374
  • [40] Effects of LiF on the properties of (Ba, Ca)(Ti, Sn, Hf)O3-based multilayer ceramics co-fired with Ni at reduced atmosphere
    Yu, Mei-Chieh
    Tsai, Cheng-Che
    Hong, Cheng-Shong
    Zhang, Yuan-Xin
    Feng, Guang-Huan
    Chu, Sheng-Yuan
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2023, 106 (02) : 1037 - 1049