The facile hydrolysis of chlorine nitrate in aqueous sulfate aerosols

被引：4
|
作者：
McNamara, JP [1 ]
Hillier, IH [1 ]
机构：
[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
来源：
CHEMICAL PHYSICS LETTERS | 2000年 / 328卷 / 4-6期
关键词：
D O I：
10.1016/S0009-2614(00)00950-7
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
High level electronic structure calculations show that chlorine nitrate is readily hydrolysed in aqueous sulfate aerosols. For the reaction catalysed by H2SO4 and three water molecules, the reaction products involve H3O+NO3-/H2SO4/HOCl. Catalysis by HSO4- leads to an essentially spontaneous reaction, where the reaction products involve NO3-/H2SO4/HOCl or HONO2/HSO4-/HOCl depending on the size of the water cluster. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：492 / 499
页数：8
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