Rhodium-Catalyzed C-H Bond Arylation of Arenes

被引：115

作者：

Bouffard, Jean ^{[1
]}

Itami, Kenichiro ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Sci, Dept Chem, Chikusa Ku, Nagoya, Aichi 4648602, Japan

来源：

C-H ACTIVATION | 2010年 / 292卷

基金：

日本科学技术振兴机构; 日本学术振兴会;

关键词：

Biaryls; Catalysis; C-H activation; Cross-coupling; Rhodium; CROSS-COUPLING REACTIONS; CARBON-HYDROGEN-BONDS; ELECTROPHILIC AROMATIC METALATION; PROTON-ABSTRACTION MECHANISM; OXIDATIVE ADDITION; REGIOSELECTIVE ARYLATION; BIARYL SYNTHESIS; ARYL CHLORIDES; PALLADIUM; ACTIVATION;

D O I：

10.1007/128_2009_12

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms and their implications on reactivity, selectivity and substrate scope.

引用

页码：231 / 280

页数：50

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