Enthalpies of formation of liquid binary lanthanide-metal alloys

被引:1
|
作者
Jiang, LQ [1 ]
Sheng, JW [1 ]
机构
[1] Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China
关键词
D O I
10.1007/s10853-005-5708-z
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The application of Miedema's model for calculating enthalpies and unknown heat of formation of binary Lanthanide-metal alloys was investigated. The activity coefficient of Lanthanide was found to be effected by the mole fraction of Lanthanide. A linear dependency of enthalpy on molar volume was clearly observed for both calculated and measured values. The results show that the calculated values are more negative than experimental values.
引用
收藏
页码:207 / 210
页数:4
相关论文
共 50 条
  • [31] Comparison of enthalpies of formation and enthalpies of mixing in transition metal based alloys
    Colinet, C
    THERMOCHIMICA ACTA, 1998, 314 (1-2) : 229 - 245
  • [32] On the Nature of Actinide- and Lanthanide-Metal Bonds in Heterobimetallic Compounds
    Vlaisavljevich, Bess
    Miro, Pere
    Cramer, Christopher J.
    Gagliardi, Laura
    Infante, Ivan
    Liddle, Stephen T.
    CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (30) : 8424 - 8433
  • [33] Prediction of the formation enthalpies of Bi-Cd-Ga-In-Pb-Sn-Zn liquid alloys by binary infinitely dilute enthalpies
    Yang, HongWei
    Tao, DongPing
    Yang, XiaoMei
    Yuan, QingMei
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 480 (02) : 625 - 628
  • [34] Enthalpy of formation of liquid (transition metal-spmetal) binary alloys
    Gaune-Escard, M
    Bros, JP
    THERMODYMANICS OF ALLOY FORMATION, 1997, : 21 - 42
  • [35] ENTHALPIES OF FORMATION OF LIQUID ALLOYS OF COBALT AND TIN WITH TITANIUM
    ESIN, YO
    VALISHEV, MG
    ERMAKOV, AF
    GELD, PV
    PETRUSHEVSKII, MS
    ZHURNAL FIZICHESKOI KHIMII, 1981, 55 (03): : 747 - 748
  • [36] Enthalpies of formation of liquid and solid (palladium + indium) alloys
    El, Allam, Driss
    Gaune-Escard, Marcelle
    Bros, Jean-Pierre
    Hayer, Erhard
    Metallurgical and Materials Transactions B: Process metallurgy and Materials Processing Science, 1995, 26 (04):
  • [37] ENTHALPIES OF FORMATION OF LIQUID ALLOYS OF GERMANIUM AND NICKEL WITH TITANIUM
    ESIN, YO
    VALISHEV, MG
    ERMAKOV, AF
    GELD, PV
    PETRUSHEVSKII, MS
    ZHURNAL FIZICHESKOI KHIMII, 1981, 55 (03): : 753 - 754
  • [38] ENTHALPIES OF FORMATION OF LIQUID AND SOLID (GALLIUM + PALLADIUM) ALLOYS
    ELALLAM, D
    GAUNEESCARD, M
    BROS, JP
    HAYER, E
    METALLURGICAL TRANSACTIONS B-PROCESS METALLURGY, 1992, 23 (01): : 39 - 44
  • [39] Enthalpies of formation of liquid dysprosium-bismuth alloys
    Sheng, J
    Yamana, H
    Moriyama, H
    JOURNAL OF MATERIALS SCIENCE LETTERS, 2001, 20 (15) : 1393 - 1395
  • [40] ENTHALPIES OF THE FORMATION OF EUROPIUM-INDIUM LIQUID ALLOYS
    BUSHMANOV, VD
    FEDOROVA, EG
    YATSENKO, SP
    ZHURNAL FIZICHESKOI KHIMII, 1987, 61 (07): : 1797 - 1799