Towards macrocyclic frustrated Lewis pairs

被引：2
|
作者：
Yeung, Jason [1 ]
Becker, Matthias [1 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada
来源：
DALTON TRANSACTIONS | 2022年 / 51卷 / 29期
基金：
加拿大自然科学与工程研究理事会;
关键词：
RADICALS;
D O I：
10.1039/d2dt01716d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Macrocycles with and without B-N bonds were prepared from reaction of C6F5BH2 center dot SMe2 or MesBH(2) with the 2,6-pyridinedimethanol derivatives. Both classes of macrocycle reacted with B(C6F5)(3) but were unreactive to small molecules. These observations provide insights for the subsequent design of macrocyclic FLPs for multi-electron reactions.
引用
收藏
页码：10871 / 10874
页数：4
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