RECYCLIZATION REACTIONS OF 2-(1-BENZOYLPYRROLIDIN-2-YLIDENE)MALONONITRILE

被引:4
|
作者
Shvidenko, K. V. [1 ]
Nazarenko, K. G. [1 ]
Shvidenko, T. I. [2 ]
Tolmachev, A. A. [3 ]
机构
[1] Natl Acad Sci Ukraine, Inst Organ Chem, UA-02094 Kiev, Ukraine
[2] Natl Agr Univ Ukraine, UA-03041 Kiev, Ukraine
[3] Kiev T Shevchenko Natl Univ, Res & Dev Ctr Chem & Biol, UA-01033 Kiev, Ukraine
关键词
omega-aminoalkylheterocycles; binucleophiles; cyclic enamines; recyclization;
D O I
10.1007/s10593-010-0469-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Acylation of pyrrolidin-2-ylidenemalononitrile with benzoyl chloride leads to the formation of 2-(1-benzoylpyrrolidin-2-ylidene) malononitrile. The obtained product was used as starting material in the synthesis of gamma-aminopropylpyrazoles and pyrimidines.
引用
收藏
页码:56 / 60
页数:5
相关论文
共 50 条
  • [41] 2-[2-(4-Nitrophenyl)hydrazinylidene]malononitrile
    Han, Lu-Na
    Zhang, Min
    Lu, Ran-Zhe
    Wei, Wen-Bin
    Wang, Hai-Bo
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O196 - U2777
  • [42] Crystal structure of 2-(3,5,5-trimethylcyclohex-2-en-1-ylidene)malononitrile, C12H14N2
    Liu, Yingfan
    Wang, Mengfei
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2023, 238 (05): : 995 - 997
  • [43] Synthesis of 2-(3-Cyanofuran-2(5H)-ylidene)malononitrile Derivative and Its Recognition for Pd2+
    Zhong, Keli
    Zhou, Lulu
    Chen, Lin
    Tang, Lijun
    Gao, Xue
    Liu, Xiuying
    Pang, Xiuxiu
    Yan, Xiaomei
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2021, 41 (03) : 1124 - 1130
  • [44] Synthesis of spiro heterocyclic systems from 2-(3-oxoisobenzofuran-1(3H)-ylidene)malononitrile and binucleophiles
    Diyanatizadeh, Mohammad Hadi
    Yavari, Issa
    JOURNAL OF CHEMICAL RESEARCH, 2017, (06) : 330 - 332
  • [45] Electroluminescent copolymers based on dihexylfluorene and 2-{2,6-bis[2-(4-diphenylaminophenyl)vinyl] pyran-4-ylidene}malononitrile units
    Kim, Joo Hyun
    You, Nam-Ho
    Lee, Hoosung
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2006, 44 (12) : 3729 - 3737
  • [46] Reassignment of the Structures of Products Produced by Reactions of the Product Believed To Be 2-(1-Phenyl-2-Thiocyanatoethylidene)-malononitrile with Electrophiles
    Al-Mousawi, Saleh Mohammed
    Moustafa, Moustafa Sherief
    Elnagdi, Mohamed Hilmy
    MOLECULES, 2011, 16 (05) : 3456 - 3468
  • [47] 2-{2-[(E)-(2-Benzoylhydrazin-1-ylidene)methyl]phenoxy}acetic acid
    Fun, Hoong-Kun
    Chia, Tze Shyang
    Alafeefy, Ahmed M.
    Abdel-Aziz, Hatem A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2260 - +
  • [48] 2-[2-(4-Methoxyphenyl)-2-oxoethyl]malononitrile
    Lian, Mi
    Chen, Tianli
    Zhu, Yanping
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2007 - U261
  • [49] Molecular modeling and cyclization reactions of 2-(4-oxothiazolidine-2-ylidene) acetonitrile
    G. A. M. Elhagali
    G. A. Elsayed
    R. A. Eliswey
    A. A. El-Sherif
    Journal of the Iranian Chemical Society, 2018, 15 : 1243 - 1254
  • [50] Molecular modeling and cyclization reactions of 2-(4-oxothiazolidine-2-ylidene) acetonitrile
    Elhagali, G. A. M.
    Elsayed, G. A.
    Eliswey, R. A.
    El-Sherif, A. A.
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2018, 15 (06) : 1243 - 1254