New development of photo-induced electron transfer reaction and total synthesis of natural product

被引：2
|
作者：
Hamada, T [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Kita Ku, Sapporo, Hokkaido 0600812, Japan
来源：
YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN | 2005年 / 125卷 / 01期
关键词：
photo-induced electron transfer; face selective Diels-Alder; cannabisativine; macrolide synthesis; conformation calculation;
D O I：
10.1248/yakushi.125.1
中图分类号：
R9 [药学];
学科分类号：
1007 ;
摘要：
Some new developments of photochemical one-electron transfer reactions are described, and reaction mechanisms are discussed. Application of catalytic photoelectron transfer (photo-cleavage of sulfonamide) to the total synthesis of (-) -cannabisativine is also reported. In order to develop new synthetic methodology, conformational analysis of macrolide seco-acid is presented, and the design and application of seco-acids to the first total synthesis of lankanolide is also disclosed.
引用
收藏
页码：1 / 16
页数：16
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