Hydroperoxides and aryl diazonium salts as reagents for the functionalization of non-activated olefins

被引：17
|
作者：
Blank, Olga [1 ]
Raschke, Nicole [1 ]
Heinrich, Markus R. [1 ,2 ]
机构：
[1] Tech Univ Munich, D-85747 Garching, Germany
[2] Univ Erlangen Nurnberg, D-91052 Erlangen, Germany
来源：
TETRAHEDRON LETTERS | 2010年 / 51卷 / 13期
关键词：
Radical reactions; Hydroperoxides; Olefin functionalization; Arenediazonium salts; ALPHA-ALKOXY HYDROPEROXIDES; FREE-RADICAL REACTIONS; REDUCTIVE CARBODIAZENYLATION; FRAGMENTATION REACTIONS; NITROGEN BONDS; POLAR; CARBOAZIDATION; AZIDATION; CARBON; CONVENIENT;
D O I：
10.1016/j.tetlet.2010.01.098
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Hydroperoxides, olefins, and arenediazonium salts selectively combine to give azo compounds via an iron(II)-mediated three-component reaction. Starting with a fragmentation liberating acetic acid, the hydro-peroxides act as radical source and the diazonium ions as nitrogen-centered radical scavengers. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码：1758 / 1760
页数：3
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