Delta function model for the helium trimer: origin of three-body forces

被引:6
|
作者
Blinder, SM [1 ]
Lohr, LL [1 ]
机构
[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA
关键词
D O I
10.1080/00268970010000458
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The Dirac bubble potential, previously used to model the helium dimer, is applied to the trimer. It is shown that the quantum mechanical kinetic energy operator for a three-body system contains terms over and above the analogues of classical pairwise contributions. The additional terms, the 'Borromean couplings', are responsible for a dramatic increase in the binding energy of the trimer. For example, He-4(3) is bounded by two orders of magnitude more strongly than He-4(2), 279 mK versus 1.31 mK, respectively, according to our calculations. Moreover, the trimer is considerably more compact than the dimer, with [r(12)] decreasing to 9.01 Angstrom from 51.9 Angstrom.
引用
收藏
页码:53 / 56
页数:4
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