Crystal and molecular structure of 1-methyl-1,2-dinitroguanidine

被引：3

作者：

Vasiliev, AD ^{[1
]}

Astakhov, AM

Molokeev, MS

Kruglyakova, LA

Stepanov, RS

机构：

[1] LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia

[2] Siberian State Technol Univ, Krasnoyarsk, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2004年 / 45卷 / 03期

关键词：

energetic compounds; nitrimines; nitroguanidine derivatives; structure of molecular crystals;

D O I：

10.1007/s10947-005-0025-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In 1-methyl-1,2-dinitroguanidine, the nitroguanyl group has planar geometry with an intramolecular hydrogen bond, although the conformation of the whole molecule is slightly nonplanar. Because of electron density delocalization, the C-N, N-N, and N-O bond lengths are intermediate between the corresponding values for the single and double bonds. The distinction of the crystal structure is the absence of intermolecular hydrogen bonds.

引用

页码：532 / 536

页数：5

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