[Tb(pyrazinecarboxylic acid)3(H2O)2] • 6n H2O: synthesis, structure and photoluminescence

被引：2

作者：

Chen, Wentong ^{[1
]}

Yao, Zhongliang ^{[2
]}

Ying, Shaoming ^{[1
]}

Liu, Dongsheng ^{[1
]}

Liu, Jiuhui ^{[1
]}

机构：

[1] Jinggangshan Univ, Jiangxi Prov Key Lab Coordinat Chem, Sch Chem & Chem Engn, Jian 343009, Jiangxi, Peoples R China

[2] Fujian Normal Univ, Fuqing Branch, Dept Biol & Chem Engn, Fuqing 350300, Fujian, Peoples R China

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS | 2010年 / 225卷 / 01期

关键词：

Hydrothermal reaction; Lanthanide; Photoluminescence; Pyrazinecarboxylic acid; Single-crystal structure analysis; X-ray diffraction; PHOTOPHYSICAL PROPERTIES; CRYSTAL-STRUCTURE; COORDINATION POLYMERS; LANTHANIDE COMPLEXES; LUMINESCENCE; TB(III); DICARBOXYLATE; CHEMISTRY; EU(III); LIGANDS;

D O I：

10.1524/zkri.2010.1200

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A novel terbium compound [Tb(pyrazinecarboxylic acid)(3)(H2O)(2)] center dot 6n H2O (1) has been prepared via hydrothermal reaction and structurally characterized by single-crystal X-ray diffraction. The crystal belongs to the orthorhombic, space group Pbca with a = 19.4112(7), b = 11.9345(4), c = 19.8507(7) angstrom, V = 4598.7(3) angstrom(3), Z = 8, C15H25N6O14Tb, M-r= 672.33, D-c = 1.942 g/cm(3), S = 1.052, mu(MoK alpha) = 3.159 mm(-1), F(000) = 2672, R = 0.0190 and wR = 0.0423. Compound 1 features an infinite 1-D chain-like structure with the terbium ions coordinating to six oxygen and three nitrogen atoms to give a distorted monocapped square antiprism. The [Tb(pyrazinecarboxylic acid)(3)(H2O)(2)](n) chains and the lattice water molecules link to each other through pi-pi interactions and hydrogen bonding interactions to construct a 3-D supramolecular network. Photoluminescent investigation reveals that the title compound displays strong emissions that are attributed to the characteristic emissions of D-5(4) -> 7F(J) (J = 3, 4, 5, 6) of Tb3+ ions.

引用

页码：41 / 45

页数：5

共 50 条

[31] The water trimer reaction OH + (H2O)3 → (H2O)2OH + H2O
Gao, Aifang
Li, Guoliang
Peng, Bin
Weidman, Jared D.
Xie, Yaoming
Schaefer, Henry F.
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020, 22 (17) : 9767 - 9774
[32] The crystal structure of MoO2(O2)(H2O)•H2O
Reid, Joel W.
Kaduk, James A.
Matei, Lidia
[J]. POWDER DIFFRACTION, 2019, 34 (01) : 44 - 49
[33] Synthesis and Crystal Structure of [Ni（C5H2N2O4）(2,2'bipy)（H2O）2]·H2O
LI Xing CAO Rong② SUN Dao-Feng HONG Mao-Chun② (State Key Laboratory of Structural Chemistry
[J]. Chinese Journal of Structural Chemistry, 2002, (04) : 374 - 377
[34] Synthesis and crystal structure of [phenH] [La(NO3)4(H2O) (phen)] • H2O
Wu, DM
Lin, X
Lu, CZ
Zhuang, HH
[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (01) : 69 - 73
[35] Synthesis,PropertiesandCrystalStructureofaNovelCoordinatedPolymer:{（H2en）(H3O)[(BiPb（C2O4）4（H2O）2)]·2（H2O）}_n
GUO WenJuna ZHANG HanHuia b HUANG ChangCanga SUN RuiQinga CHEN YiPinga CAO YanNinga a Department of Chemistry Fuzhou University Fuzhou China bState Key Laboratory of Structural Chemistry Fuzhou China
[J]. 结构化学, 2005, (07) : 846 - 850+740
[36] Ferromagnetism in malonato-bridged copper(II) complexes.: Synthesis, crystal structures, and magnetic properties of {[Cu(H2O)3][Cu(mal)2(H2O)]}n and {[Cu(H2O)4]2[Cu(mal)2(H2O)]}[Cu(mal)2(H2O)2]{[Cu(H2O)4][Cu(mal)2(H2O)2]} (H2mal = malonic acid)
Ruiz-Pérez, C
Sanchiz, J
Molina, MH
Lloret, F
Julve, M
[J]. INORGANIC CHEMISTRY, 2000, 39 (07) : 1363 - 1370
[37] Synthesis and crystal structures of [Al(H2O)6](SO4)NO3•2H2O and [Al(H2O)6](SO4)Cl•H2O
Svensson, Fredric G.
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2021, 77 : 58 - +
[38] Synthesis and Crystal Structure of CaCo(H2O)[BP2O8(OH)] • H2O
Menezes, Prashanth W.
Hoffmann, Stefan
Prots, Yurii
Kniep, Ruediger
[J]. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2009, 635 (4-5): : 614 - 617
[39] SupramolecularTerbium-SIPComplexPillaredby4,4'-Bipyridyl,{[Tb（SIP）(H2O)5]2（bpy）3（H2O）}n:Synthesis,CrystalStructureandPhotoluminescence
王玉玲
刘庆燕
徐立
钟声亮
[J]. 结构化学, 2008, (03) : 362 - 368
[40] Syntheses and structures of p-HOOCC6F4COOH • H2O (H2L • H2O) and luminescent coordination polymers [Tb2(H2O)4(L)3 • 2H2O] n and Tb2(Phen)2(L)3 • 2H2O
Larionov, S. V.
Myachina, L. I.
Glinskaya, L. A.
Korol'kov, I. V.
Uskov, E. M.
Antonova, O. V.
Karpov, V. M.
Platonov, V. E.
Fadeeva, V. P.
[J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2012, 38 (12) : 717 - 723

← 1 2 3 4 5 →