TPR of Pd/MnO2 and Pd/Fe2O3 systems -: effects of hydrogen spillover

被引:15
|
作者
Xu, GP [1 ]
Zhu, YX [1 ]
Ma, J [1 ]
Yan, HJ [1 ]
Xie, YC [1 ]
机构
[1] Peking Univ, Inst Phys Chem, Beijing 100871, Peoples R China
关键词
D O I
10.1016/S0167-2991(97)80854-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Temperature programmed reduction of Pd/MnO2 and Pd/Fe2O3 systems were investigated. The results show that the presence of Pd lowers the reduction temperature of MnO2 and Fe2O3 due to hydrogen spillover from Pd to the oxides. Thus developed oxygen getter Pd/MnO2 can be regenerated at lower temperature and can absorb more oxygen at room temperature than the traditional oxygen getter.
引用
收藏
页码:333 / 338
页数:6
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