TPR of Pd/MnO2 and Pd/Fe2O3 systems -: effects of hydrogen spillover

被引:15
|
作者
Xu, GP [1 ]
Zhu, YX [1 ]
Ma, J [1 ]
Yan, HJ [1 ]
Xie, YC [1 ]
机构
[1] Peking Univ, Inst Phys Chem, Beijing 100871, Peoples R China
关键词
D O I
10.1016/S0167-2991(97)80854-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Temperature programmed reduction of Pd/MnO2 and Pd/Fe2O3 systems were investigated. The results show that the presence of Pd lowers the reduction temperature of MnO2 and Fe2O3 due to hydrogen spillover from Pd to the oxides. Thus developed oxygen getter Pd/MnO2 can be regenerated at lower temperature and can absorb more oxygen at room temperature than the traditional oxygen getter.
引用
收藏
页码:333 / 338
页数:6
相关论文
共 50 条
  • [1] MnO2/Fe2O3 Nanocomposite Sorbent for Gas Capture
    Ma, Xiaowei
    Yang, Rui
    Doig, Renny
    Liu, Aaron
    Rankin, Matthew A.
    Cro, Lisa M.
    Zhang, Peng
    Dahn, J. R.
    ACS APPLIED NANO MATERIALS, 2018, 1 (12): : 6674 - 6682
  • [2] Structural transformation of Pd-α-Fe2O3 and Pd-γ-Fe2O3 catalysts and application in the CO oxidation reaction
    Xu, Hong
    Ni, Ke
    Li, Xiaokun
    Fang, Guangzong
    Fan, Guohong
    RSC ADVANCES, 2017, 7 (81): : 51403 - 51410
  • [3] Water–Gas Shift on Pd/α-MnO2 and Pt/α-MnO2
    Jun-jun Shan
    Luan Nguyen
    Shiran Zhang
    Franklin-Feng Tao
    Catalysis Letters, 2015, 145 : 1571 - 1580
  • [4] Kinetics of aluminothermic reduction of MnO2 and Fe2O3: A thermoanalytical investigation
    Sarangi, B
    Sarangi, A
    Ray, HS
    ISIJ INTERNATIONAL, 1996, 36 (09) : 1135 - 1141
  • [5] Pure hydrogen production by steam-iron process: The synergic effect of MnO2 and Fe2O3
    De Filippis, Paolo
    D'Alvia, Livio
    Damizia, Martina
    de Caprariis, Benedetta
    Del Prete, Zaccaria
    INTERNATIONAL JOURNAL OF ENERGY RESEARCH, 2021, 45 (03) : 4479 - 4494
  • [6] Effects of MnO2 and Fe2O3 on microstructure and crush resistance of alumina matrix fracturing proppant
    Ma, Xue
    Yao, Xiao
    Hua, Sudong
    Chen, Yue
    Kuei Suan Jen Hsueh Pao/ Journal of the Chinese Ceramic Society, 2009, 37 (02): : 280 - 284
  • [7] Selective oxidation of cyclohexane at low temperature by Fe-Pd bicatalytic systems;: FeCl2-Pd/alumina system and Pd/Fe2O3 system
    Jun, KW
    Nakka, L
    Kim, SB
    Lee, KW
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1997, 18 (12) : 1269 - 1273
  • [8] Fabrication and Improved Photocatalytic Performance of Pd/α-Fe2O3
    He, Jinjin
    Zhong, Junbo
    Li, Jianzhang
    Huang, Shengtian
    Zeng, Jun
    SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (05) : 673 - 677
  • [9] A comparative study of in-situ mechanochemically synthesized Mn0.5Zn0.5Fe2O4 ferrite nanoparticles in the MnO/ZnO/Fe2O3 and MnO2/Zn/Fe2O3 systems
    Hajalilou, Abdollah
    Hashim, Mansor
    Masoudi, Mohamad Taghi
    CERAMICS INTERNATIONAL, 2015, 41 (06) : 8070 - 8079
  • [10] Water-Gas Shift on Pd/α-MnO2 and Pt/α-MnO2
    Shan, Jun-jun
    Luan Nguyen
    Zhang, Shiran
    Tao, Franklin-Feng
    CATALYSIS LETTERS, 2015, 145 (08) : 1571 - 1580