Influence of the concentration of carbon nanotubes on electrical conductivity of magnetically aligned MWCNT-polypyrrole composites

被引:3
|
作者
Kazemikia, Kaveh [1 ]
Bonabi, Fahimeh [2 ]
Asadpoorchallo, Ali [3 ]
Shokrzadeh, Majid [4 ]
机构
[1] Islamic Azad Univ, Dept Elect & Comp Engn, Bonab Branch, Bonab 55591, Iran
[2] Islamic Azad Univ, Dept Engn, Bonab Branch, Bonab 55591, Iran
[3] Islamic Azad Univ, Sci & Res Branch, Tehran 50122, Iran
[4] Univ Tabriz, Dept Chem, Tabriz 51999, Iran
关键词
Pulsed magnetic field; CNT alignment; polypyrrole; AFM; RLC circuit; POLYMER COMPOSITES; NANOCOMPOSITES; FIELD; ALIGNMENT;
D O I
10.1007/s12034-016-1169-z
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The goal of this work is to study the effect of high magnetic pulses on electrical property of carbon nanotube-polypyrrole (CNT-PPy) composites with different CNT concentrations. CNT-PPy composites are produced in fractions of 1, 5 and 9 wt%. During the polymerization process, the CNTs are homogeneously dispersed throughout the polymer matrix in an ultrasonic bath. Nanocomposite rods are prepared. After exposure to 30 magnetic pulses, the resistivity of the rods is measured. The surface conductivity of thin tablets of composites is studied by 4-probe technique. The magnitude of the pulsed magnetic field is 10 Tesla with time duration of 1.5 ms. The results show that after applying 30 magnetic pulses, the electrical resistivity of the composites decreases depending on the concentration of CNTs in the composites. The orientation of CNTs is probed by atomic force microscopy (AFM) technique. AFM images approved alignment of CNT-polymer fibres in the magnetic field. We found that the enhancement in the electrical properties of CNT-PPy composites is due to rearrangement and alignment of CNTs in a high magnetic field. The stability of nano-composites is studied by Fourier transform infrared spectroscopy.
引用
收藏
页码:457 / 462
页数:6
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