Preparation, characterization and catalytic properties of CuPC/Y nano-composite

被引：0
|
作者：
Yang, HX [1 ]
Li, RF [1 ]
Xie, KC [1 ]
机构：
[1] Taiyuan Univ Technol, State Key Lab C1 Chem & Technol, Inst Special Chem, Taiyuan 030024, Peoples R China
来源：
NANOPOROUS MATERIALS III | 2002年 / 141卷
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Well-crystallized CuPC/zeolite Y nano-composite of average particle size less than 80nm (denoted as CuPC/nano-Y) has been successfully synthesized via zeolite synthesis route. The nano-zeolite host was confirmed by the XRD and TEM. The CuPC complexes entrapped in the nano-hosts were characterized by XRD, TEM, FTIR, TG/DTA, ICP and UV-vis. CuPC/Y samples with different particle sizes in micro-scale were also synthesized by adjusting the synthesis conditions. Under the mild situation (60degreesC, 1atm), CuPC in nano-Y exhibits the catalytic activity 2.1 times higher than CuPC in normal Y with particle size of 500nm for the liquid phase oxidation of cyclohexane using aqueous H2O2 (30wt.%) as the oxidant.
引用
收藏
页码：575 / 582
页数：8
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