Syntheses and characterizations of transition metal-doped ZnO

被引:41
|
作者
Jung, Dongwoon [1 ,2 ]
机构
[1] Wonkwang Univ, Dept Bionano Chem, Iksan 570749, Jeonbuk, South Korea
[2] Wonkwang Univ, Inst Nat Basic Sci, Iksan 570749, Jeonbuk, South Korea
关键词
Zinc oxide; Photocatalyst; Co-precipitation method; Doping; Band gap; THIN-FILMS; GROWTH;
D O I
10.1016/j.solidstatesciences.2009.12.009
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The transition metal-doped zinc oxides, Zn1-xMxO (M = Cu, Mn and Fe) were synthesized by using solid-state reaction method and co-precipitation method. Samples prepared by co-precipitation method showed exactly same structure and properties compared to those made by solid-state reaction method. XRD, XRF and mapping analyses showed that Zn was successfully substituted with Cu, Mn and Fe by co-precipitation method. Zn1-xMxO samples exhibited new absorption shoulder in visible light region so that they showed photocatalytic activity in the visible light region. The highest photocatalytic activity under visible light was found in the Mn-substituted zinc oxide. (C) 2009 Elsevier Masson SAS. All rights reserved.
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页码:466 / 470
页数:5
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