Synthesis and reactivity of the ferrocene-derived phosphine [Fe(eta-C5H5)-{eta-C5H4CH2P(CH2OH)(2)}]

被引：43

作者：

Goodwin, NJ

Henderson, W

Nicholson, BK

Sarfo, JK

Fawcett, J

Russell, DR

机构：

[1] UNIV WAIKATO,DEPT CHEM,HAMILTON,NEW ZEALAND

[2] UNIV LEICESTER,DEPT CHEM,LEICESTER LE1 7RH,LEICS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1997年 / 22期

关键词：

D O I：

10.1039/a703666c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The air-stable compound [Fe(eta-C5H5){eta-C5H4CH2P(CH2OH)(2)}] 1 has been prepared by the reaction of [Fe-(eta-C5H5)(eta-C5H4CH2NMe3)]I with an excess of P(CH2OH)(3). Compound 1 has been used to produce a range of other new compounds, thus demonstrating its versatility as a starting material; the phosphine oxide [Fe(eta-C5H5) {eta-C5H4CH2P(O)(CH2OH)(2)}] 2, phosphine sulfide [Fe(eta-C5H5){eta-C5H4CH2P(S)(CH2OH)(2)}] 3, and other derivatives [Fe(eta-C5H5){eta-C5H4CH2P(CH2CH2CN)(2)}] 4, [Fe(eta-C5H5){eta-C5H4CH2P(CH2NEt2)(2)}] 5, [Fe(eta-C5H5){eta-C5H4CH2P(O)(CH2NEt2)(2)}] 6, [Fe(eta-C5H5){eta-C5H4CH2P(Me)(CH2OH)(2)}]I 7 and [Fe(eta-C5H5)-{eta-C5H4CH2P(Me)CH2OH}] 8. Crystal structure determinations for 1, 3 and 7 are reported and the hydrogen bonding of each structure described.

引用

页码：4377 / 4384

页数：8

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