Synthesis and characterisation of the fullerene co-crystal C60*SiH(C6H5)3

被引：0

作者：

Waidmann, G ^{[1
]}

Jansen, M ^{[1
]}

机构：

[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1998年 / 53卷 / 02期

关键词：

fullerene C-60; synthesis; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new fullerene co-crystal C-60*SiH(C6H5)(3) has been synthesized by crystallisation from a melt of SiH(C6H5)(3) and C-60 in sealed duran tubes at 80 degrees C. X-ray investigations led to triclinic symmetry, space group P (1) over bar, a = 10.086(1), b = 14.431(2), c = 14.911(2) Angstrom, alpha = 79.13(1), beta = 74.943(9), gamma = 88.33(1)degrees, V = 2058.0(4) Angstrom(3), Z = 2. The crystal structure consists of isolated fullerene and silane molecules. At -80 degrees C, C-60 is still rotationally disordered. Temperature dependent Guinier powder diagrams do not show any phase transformation between 25 and -165 degrees C. The compound is stable in air.

引用

页码：161 / 164

页数：4

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