Adhesion strength study between plasma treated polyester fibres and a rubber matrix

被引:48
|
作者
Krump, H
Simor, M
Hudec, I
Jasso, M
Luyt, AS
机构
[1] Univ Free State, Dept Chem, ZA-9866 Phuthaditjhaba, South Africa
[2] TNO, PML, Prins Maurits Lab, NL-2280 AA Rijswijk, Netherlands
[3] Slovak Univ Technol Bratislava, Dept Plast & Rubber, Bratislava, Slovakia
关键词
adhesion strength; atmospheric plasma treatment; poly(ethylene terephthalate); styrene-butadiene rubber (SBR); lubricants; ageing; GC-MS;
D O I
10.1016/j.apsusc.2004.06.109
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this work, the adhesion strength between poly(ethylene terephthalate) (PET) fibres and styrene-butadiene rubber (SBR) was studied. The effects of atmospheric plasma treatment, used to increase adhesion strength between PET fibres and the rubber matrix, were investigated and compared. It was confirmed that lubricants on the fibres caused a decrease in adhesion strength between the plasma treated reinforcing PET fibres and the SBR rubber matrix. These lubricants can be removed by acetone. When washed and treated in plasma, a substantial improvement in adhesion strength was observed. No ageing in air before combination with the rubber matrix was observed. This confirmed that the plasma streamers caused the creation of a new, relatively stable chemical species on the polymer surface. It suggests that the surface modification of PET fibres by plasma treatment at atmospheric gas pressure is a suitable and technologically applicable method for the improvement of adhesion strength of polyester reinforcing materials to rubber. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:268 / 274
页数:7
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