Synthesis, Crystal Structure, and Luminescent Activity of 3D Supramolecular Cadmium(II) Complex Constructed From 2,5-Pyridine Dicarboxylic Acid

被引：7

作者：

Gangu, Kranthi Kumar ^{[1
]}

Mukkamala, Saratchandra Babu ^{[1
]}

机构：

[1] GITAM Univ, Dept Chem, Visakhapatnam 530045, Andhra Pradesh, India

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2016年 / 46卷 / 01期

关键词：

hydrothermal synthesis; crystal structure; supramolecular network; photoluminescence; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESIS; FRAMEWORK; LIGANDS; CHAIN; PHOTOLUMINESCENCE; PROPERTY;

D O I：

10.1080/15533174.2014.900788

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D supramolecular cadmium(II) complex, [Cd(Pydc)(2)(H2O)(2)].H2O(1), (Pydc = 2,5-pyridine dicarboxylate) has been synthesized under mild hydrothermal conditions. In the complex, the two adjacent Cd(II) atoms were bound together by two -oxo bridging and generated an infinite straight chains in 2D layer structure. The non-covalent interactions such as - stacking interactions between pyridyl rings are involved in strengthening of 2D structure and hydrogen bond interactions between two adjacent chains through lattice water molecules led to form an extended 3D supramolecular network structure. Moreover, complex 1 exhibits blue emission at 437nm after photo excitation at 365nm.

引用

页码：98 / 103

页数：6

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