Direct Synthesis of Dimethyl Ether (DME) from Syngas

被引:0
|
作者
Takeishi, Kaoru [1 ]
Akaike, Yoshimi [1 ]
机构
[1] Shizuoka Univ, Dept Mat Sci & Chem Engn, Naka Ku, 3-5-1 Jouhoku, Hamamatsu, Shizuoka 4328561, Japan
关键词
Dimethyl ether; DME; hydrogen; clean fuel; catalyst; sol-gel method; alumina; copper; direct synthesis; syngas;
D O I
暂无
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
We have developed appropriate and excellent catalysts for direct DME synthesis. The catalysts, Cu-Zn/Al2O3 catalysts prepared by the sol-gel method, produce DME with high DME activity and high DME selectivity under milder reaction temperature and pressure compared with the usual direct DME synthesis catalysts (mixed catalysts of methanol synthesis catalysts and methanol dehydration catalysts). It will be the reason why the methanol synthesis active sites (copper) and the methanol dehydration active sites (alumina) on the sol-gel Cu/Al2O3 catalysts exist closer than those of the mixed catalysts.
引用
收藏
页码:408 / +
页数:3
相关论文
共 50 条
  • [41] Modelling-based Optimisation of the Direct Synthesis of Dimethyl Ether from Syngas in a Commercial Slurry Reactor
    Papari, Sadegh
    Kazemeini, Mohammad
    Fattahi, Moslem
    [J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2013, 21 (06) : 611 - 621
  • [42] Simulation and model design of pipe-shell reactor for the direct synthesis of dimethyl ether from syngas
    Yanfang Hu~1 Zhaoguang Nie~(1*) Dingye Fang~2 1.College of Chemical Engineering and Environment
    2.Department of Chemical Engineering
    [J]. Journal of Energy Chemistry, 2008, (02) : 195 - 200
  • [43] Pilot-scale tests of direct dimethyl ether synthesis from biomass-derived syngas
    Li, Yuping
    Wang, Tiejun
    Yin, Xiuli
    Wu, Chuangzhi
    Ma, Longlong
    Li, Haibin
    Zhang, Xinghua
    Lv, Yongxing
    Li, Yuping
    [J]. 2009 ASIA-PACIFIC POWER AND ENERGY ENGINEERING CONFERENCE (APPEEC), VOLS 1-7, 2009, : 484 - 487
  • [44] Simulation and model design of pipe-shell reactor for the direct synthesis of dimethyl ether from syngas
    Hu, Yanfang
    Nie, Zhaoguang
    Fang, Dingye
    [J]. JOURNAL OF NATURAL GAS CHEMISTRY, 2008, 17 (02): : 195 - 200
  • [45] Hydrogen Production from Dimethyl Ether (DME)
    Takeishi, Kaoru
    Suzuki, Hiromitsu
    [J]. RECENT ADVANCES IN ENERGY AND ENVIRONMENT, 2010, : 396 - +
  • [46] LDH-Derived (CuZn)xAly Bifunctional Catalyst for Direct Synthesis of Dimethyl Ether from Syngas
    Tian, Sha
    Tan, Minghui
    Ma, Qingxiang
    Wu, Xuemei
    Luan, Chunhui
    Fang, Yuan
    Li, Hangjie
    Yang, Guohui
    Tsubaki, Noritatsu
    Tan, Yisheng
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2020, 59 (23) : 11087 - 11097
  • [47] An evaluation of direct dimethyl ether (DME) synthesis from hydrogen and carbon dioxide based on CFD reactor simulations
    Beltermann, Nils
    Weiske, Stefan
    Becka, Rafael
    Samsun, Remzi Can
    Peters, Ralf
    Stolten, Detlef
    Mueller, Thomas E.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2023, 48 (99) : 39373 - 39388
  • [48] Simulation of single-step dimethyl ether synthesis from syngas
    Polsen, Chanida
    Narataruksa, Phavanee
    Hunpinyo, Piyapong
    Prapainainar, Chaiwat
    [J]. ENERGY REPORTS, 2020, 6 : 516 - 520
  • [49] Specifics of dimethyl ether synthesis from syngas over mixed catalysts
    Lishchiner I.I.
    Malova O.V.
    Tarasov A.L.
    Korobtsev S.V.
    Krotov M.F.
    Potapkin B.V.
    [J]. Catalysis in Industry, 2016, 8 (3) : 205 - 212
  • [50] Embryonic zeolites for highly efficient synthesis of dimethyl ether from syngas
    Palcic, Ana
    Jaen, Sara Navarro
    Wu, Dan
    Cai, Mengdie
    Liu, Chong
    Pidko, Evgeny A.
    Khodakov, Andrei Y.
    Ordomsky, Vitaly
    Valtchev, Valentin
    [J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2021, 322