Ba2PO4I, Sr2PO4I, and Pb2PO4I - A New Structure Type and Three of Its Representatives

被引：3
|
作者：
Haberkorn, Robert [1 ]
Bauer, Jessica [1 ]
Kickelbick, Guido [1 ]
机构：
[1] Univ Saarland, D-66041 Saarbrucken, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2014年 / 640卷 / 15期
关键词：
X-ray diffraction; Structure determination; Rietveld analysis; Lead; CRYSTAL-STRUCTURE; SPODIOSITE; CHLOROPHOSPHATE; FLUOROPHOSPHATE; CA2ASO4CL; WAGNERITE; APATITE; ANALOGS;
D O I：
10.1002/zaac.201400221
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compound Pb2PO4I was synthesized via a solid state reaction under inert conditions. None of the known structure types of other compounds of the type M-2(P,V,As,Cr)O-4(F,Cl,Br,I) provided a similar pattern. Structure solution was carried out by evaluation of an X-ray diffractogram of polycrystalline powder using the methods simulated annealing and difference Fourier. Pb2PO4I crystallizes in the space group P2(1)/c with the lattice parameters a = 9.0451(1) angstrom, b = 8.7593(1)angstrom, c = 8.5740(1) angstrom, and beta = 111.128(1)degrees. The isotypic compounds Sr2PO4I and Ba2PO4I were synthesized, too. Their crystallographic structure was refined by Rietveld analysis. The structure of the three compounds is described and discussed.
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收藏
页码：3153 / 3158
页数：6
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