Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands

被引：176
|
作者：
Inagaki, Tomohiko [1 ]
Phong, Le Thanh [1 ]
Furuta, Akihiro [1 ]
Ito, Jun-ichi [1 ]
Nishiyama, Hisao [1 ]
机构：
[1] Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 10期
基金：
日本学术振兴会;
关键词：
asymmetric catalysis; bisoxazoline ligands; cobalt; hydrosilylation; iron; FRIEDEL-CRAFTS ALKYLATION; C-2-SYMMETRIC TRIDENTATE BIS(OXAZOLINE); ENANTIOSELECTIVE BOROHYDRIDE REDUCTION; CARBONYL-COMPOUNDS; TRANSFER HYDROGENATION; CONJUGATE REDUCTION; HENRY REACTION; COMPLEXES; EFFICIENT; BIS(THIAZOLINE);
D O I：
10.1002/chem.200903118
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chiral bis(oxazolinylphenyl)amines proved to be efficient auxiliary ligands for iron and cobalt catalysts with high activity for asymmetric hydrosilylation of ketones and asymmetric conjugate hydrosilylation of enones.
引用
收藏
页码：3090 / 3096
页数：7
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