Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands

被引：176
|
作者：
Inagaki, Tomohiko [1 ]
Phong, Le Thanh [1 ]
Furuta, Akihiro [1 ]
Ito, Jun-ichi [1 ]
Nishiyama, Hisao [1 ]
机构：
[1] Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 10期
基金：
日本学术振兴会;
关键词：
asymmetric catalysis; bisoxazoline ligands; cobalt; hydrosilylation; iron; FRIEDEL-CRAFTS ALKYLATION; C-2-SYMMETRIC TRIDENTATE BIS(OXAZOLINE); ENANTIOSELECTIVE BOROHYDRIDE REDUCTION; CARBONYL-COMPOUNDS; TRANSFER HYDROGENATION; CONJUGATE REDUCTION; HENRY REACTION; COMPLEXES; EFFICIENT; BIS(THIAZOLINE);
D O I：
10.1002/chem.200903118
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chiral bis(oxazolinylphenyl)amines proved to be efficient auxiliary ligands for iron and cobalt catalysts with high activity for asymmetric hydrosilylation of ketones and asymmetric conjugate hydrosilylation of enones.
引用
收藏
页码：3090 / 3096
页数：7
相关论文
共 50 条
  • [1] Cobalt-Catalyzed Asymmetric Hydrosilylation of ?-Oxygenated Ketones
    Wen, Huiting
    Chen, Yifei
    Shi, Lanxuan
    Chen, Jianhui
    Luo, Yanshu
    Xia, Yuanzhi
    ORGANIC LETTERS, 2023, 25 (13) : 2184 - 2189
  • [2] Iron- and Cobalt-Catalyzed Asymmetric Hydrofunctionalization of Alkenes and Alkynes
    Guo, Jun
    Cheng, Zhaoyang
    Chen, Jianhui
    Chen, Xu
    Lu, Zhan
    ACCOUNTS OF CHEMICAL RESEARCH, 2021, 54 (11) : 2701 - 2716
  • [3] New chiral bis(oxazolinyl) bipyridine ligands and application in the iron catalyzed asymmetric hydrosilylation of ketones
    Jalba, Angela
    Levitre, Guillaume
    Keipour, Hoda
    Lauzon, Samuel
    Ollevier, Thierry
    FRENCH-UKRAINIAN JOURNAL OF CHEMISTRY, 2015, 3 (02): : 44 - 53
  • [4] Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes
    Pal, Kuntal
    Hemming, Oliver B.
    Day, Benjamin M.
    Pugh, Thomas
    Evans, David J.
    Layfield, Richard A.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (05) : 1690 - 1693
  • [5] Insights into iron- and cobalt-catalyzed cross coupling
    Chirik, Paul
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 256
  • [6] Iminophenyl Oxazolinylphenylamine for Enantioselective Cobalt-Catalyzed Hydrosilylation of Aryl Ketones
    Chen, Xu
    Lu, Zhan
    ORGANIC LETTERS, 2016, 18 (18) : 4658 - 4661
  • [7] Iron-catalyzed asymmetric hydrosilylation of ketones
    Zuo, Ziqing
    Zhang, Lei
    Leng, Xuebing
    Huang, Zheng
    CHEMICAL COMMUNICATIONS, 2015, 51 (24) : 5073 - 5076
  • [8] Cobalt(II)-catalyzed asymmetric hydrosilylation of simple ketones using dipyridylphosphine ligands in air
    Yu, Feng
    Zhang, Xi-Chang
    Wu, Fei-Fei
    Zhou, Ji-Ning
    Fang, Wenjun
    Wu, Jing
    Chan, Albert S. C.
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2011, 9 (16) : 5652 - 5654
  • [9] Iron-, Cobalt-, and Nickel-Catalyzed Asymmetric Transfer Hydrogenation and Asymmetric Hydrogenation of Ketones
    Li, Yan-Yun
    Yu, Shen-Luan
    Shen, Wei-Yi
    Gao, Jing-Xing
    ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (09) : 2587 - 2598
  • [10] Cobalt-catalyzed asymmetric hydroboration of aryl ketones with pinacolborane
    Guo, Jun
    Chen, Jianhui
    Lu, Zhan
    CHEMICAL COMMUNICATIONS, 2015, 51 (26) : 5725 - 5727
12345