Assessing guest selectivity within metallacrown host compartments

被引：34

作者：

Lim, Choong-Sun

Van Noord, Annabel Cutland

Kampf, Jeff W.

Pecoraro, Vincent L. ^{[1
]}

机构：

[1] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA

[2] Univ Michigan, Div Biophys Res, Ann Arbor, MI 48109 USA

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 10期

关键词：

molecular compartment; metallacrown; selective recognition; host-guest chemistry;

D O I：

10.1002/ejic.200700054

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

15-MC-5 complexes associate in the solid state to form chiral compartments capable of binding guests. Using small molecular yardsticks, we are able to assess the size restrictions of these structures. Dicarboxylate guests that are too short to span the Gd-III ions are stabilized by solvates that hydrogen bond to the uncoordinated carboxylate, while guests that are too long destroy the weakly associated structure. We also demonstrate that all that is required for guest encapsulation is unsaturation of the chain connection carboxylates rather than necessitating the presence of aromaticity. (c) Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1347 / 1350

页数：4

共 50 条

[41] Guest selectivity in the supramolecular host networks fabricated by van der Waals force and hydrogen bond
Peng, Xuan
Geng, Yanfang
Zhang, Min
Cheng, Faliang
Cheng, Linxiu
Deng, Ke
Zeng, Qingdao
NANO RESEARCH, 2019, 12 (03) : 537 - 542
[42] Host-guest complexes of oligopyridine cryptands: Prediction of ion selectivity by quantum chemical calculations
Puchta, Ralph
van Eldik, Rudi
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2007, 8 (08) : 1120 - 1127
[43] Guest selectivity in complexation of β-chitin
Noishiki, Y
Kuga, S
Wada, M
Hori, I
Nishiyama, Y
MACROMOLECULES, 2004, 37 (18) : 6839 - 6842
[44] Derrida: Guest and host
Still, J
PARAGRAPH, 2005, 28 (03) : 85 - 101
[45] HOST AND GUEST + CHANOYU
SOSHITSU
CHANOYU QUARTERLY-TEA AND THE ARTS OF JAPAN, 1976, (15): : 5 - 6
[46] INOR 796-Cation-guest induced alteration of the spectroscopic properties of picolinehydroxamate-based 15-metallacrown-5 host-complexes
Nagypal, Istvan
Kormanyos, Balazs
Peintler, Gabor
Horvath, Attila K.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233 : 871 - 871
[47] Selectivity behaviour of two roof-shaped host compounds in the presence of xylene and ethylbenzene guest mixtures
Barton, Benita
Barnardo, Brandon
Hosten, Eric C.
CRYSTENGCOMM, 2021, 23 (41) : 7278 - 7288
[48] A Host-Guest Approach to Engineering Oxidase-Mimetic Assembly with Substrate Selectivity and Dynamic Catalysis
Li, Shan
Xie, Yuanyuan
Zhang, Baoli
Liu, Yuanxi
Xu, Shichao
Wu, Haifeng
Du, Ruikai
Wang, Zhen-Gang
ACS APPLIED MATERIALS & INTERFACES, 2024, 16 (34) : 45319 - 45326
[49] Optimization of the host-guest system within an OLED using different models of mobility
Adames Prada, Rosana
Ardila Vargas, Angel Miguel
PHYSICA B-CONDENSED MATTER, 2014, 455 : 85 - 88
[50] Molecular recognition: minimizing the acid–base interaction of a tunable host–guest system changes the selectivity of binding
Michael Pittelkow
Christian B. Nielsen
Anders Kadziola
Jørn B. Christensen
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2009, 63 : 257 - 266

← 1 2 3 4 5 →