Synthesis and structural identification of a highly ordered mesoporous organosilica with large cagelike pores

被引：66
|
作者：
Zhao, L [1 ]
Zhu, GS [1 ]
Zhang, DL [1 ]
Di, Y [1 ]
Chen, Y [1 ]
Terasaki, O [1 ]
Qiu, SL [1 ]
机构：
[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2005年 / 109卷 / 02期
关键词：
D O I：
10.1021/jp0465231
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Using 1,2-bis(trimethoxysilyl)ethane as organosiloxane precursor and a triblock copolymer surfactant, Pluronic F127, as template, a highly ordered mesoporous organosilica with large cagelike pores has been successfully synthesized. Its structure was resolved to be 3-D cubic Fm (3) over barm by high-resolution transmission electron microscopy. The intergrowth of hexagonal close-packed and cubic close-packed phases was observed in this material. The effect of different siliceous precursors on the mesostructure was also investigated.
引用
收藏
页码：764 / 768
页数：5
相关论文
共 50 条
  • [31] Ordered Mesoporous Alumina with Ultra-Large Pores as an Efficient Absorbent for Selective Bioenrichment
    Wei, Jing
    Ren, Yuan
    Luo, Wei
    Sun, Zhenkun
    Cheng, Xiaowei
    Li, Yuhui
    Deng, Yonghui
    Elzatahry, Ahmed A.
    Al-Dahyan, Daifallah
    Zhao, Dongyuan
    CHEMISTRY OF MATERIALS, 2017, 29 (05) : 2211 - 2217
  • [32] Template synthesis of large pore ordered mesoporous carbon
    Lu, AH
    Li, WC
    Schmidt, W
    Schüth, F
    MICROPOROUS AND MESOPOROUS MATERIALS, 2005, 80 (1-3) : 117 - 128
  • [33] Mesoporous organosilica nanoparticles with large radial pores via an assembly-reconstruction process in bi-phase
    Dang, Meng
    Li, Wei
    Zheng, Yuanyi
    Su, Xiaodan
    Ma, Xiaobo
    Zhang, Yunlei
    Ni, Qianqian
    Tao, Jun
    Zhang, Junjie
    Lu, Guangming
    Teng, Zhaogang
    Wang, Lianhui
    JOURNAL OF MATERIALS CHEMISTRY B, 2017, 5 (14) : 2625 - 2634
  • [34] Mesoporous organosilica nanoparticles with large radial pores via an assembly-reconstruction process in bi-phase
    Dang M.
    Li W.
    Zheng Y.
    Su X.
    Ma X.
    Zhang Y.
    Ni Q.
    Tao J.
    Zhang J.
    Lu G.
    Teng Z.
    Wang L.
    Journal of Materials Chemistry B, 2017, 5 (14): : 2625 - 2634
  • [35] Highly Crystalline Mesoporous C60 with Ordered Pores: A Class of Nanomaterials for Energy Applications
    Benzigar, Mercy R.
    Joseph, Stalin
    Ilbeygi, Hamid
    Park, Dae-Hwan
    Sarkar, Sujoy
    Chandra, Goutam
    Umapathy, Siva
    Srinivasan, Sampath
    Talapaneni, Siddulu Naidu
    Vinu, Ajayan
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (02) : 569 - 573
  • [36] Mesoporous titania thin film with highly ordered and fully accessible vertical pores and crystalline walls
    Koh, Chol-Won
    Lee, U-Hwang
    Song, June-Kyu
    Lee, Hae-Rim
    Kim, Min-Hye
    Suh, Myungkoo
    Kwon, Young-Uk
    CHEMISTRY-AN ASIAN JOURNAL, 2008, 3 (05) : 862 - 867
  • [37] Synthesis of multifunctional nanocomposites based on highly ordered mesoporous silica
    Zhou, Zhengyang
    Zhu, Shenmin
    Zhang, Di
    CHEMISTRY LETTERS, 2006, 35 (06) : 618 - 619
  • [38] SYNTHESIS OF HIGHLY ORDERED MESOPOROUS MATERIALS FROM A LAYERED POLYSILICATE
    INAGAKI, S
    FUKUSHIMA, Y
    KURODA, K
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (08) : 680 - 682
  • [39] Easy synthesis and supercapacities of highly ordered mesoporous polyacenes/carbons
    Zhou, Liang
    Li, Huiqiao
    Yu, Chengzhong
    Zhou, Xufeng
    Tang, Jiawei
    Meng, Yan
    Xia, Yongyao
    Zhao, Dongyuan
    CARBON, 2006, 44 (08) : 1601 - 1604
  • [40] Synthesis and Characterization of large pore size and highly ordered mesoporous molecular sieve SBA-15
    Diao, Xiang
    ADVANCES IN CHEMISTRY RESEARCH II, PTS 1-3, 2012, 554-556 : 620 - 623
12345