Acyclic pyrrole-based anion receptors: design, synthesis, and anion-binding properties

被引：51
|
作者：
Sessler, Jonathan L.
Barkey, Natalie M.
Pantos, G. Dan
Lynch, Vincent M.
机构：
[1] 1 University Station-A5300, Austin
来源：
NEW JOURNAL OF CHEMISTRY | 2007年 / 31卷 / 05期
关键词：
D O I：
10.1039/b615673h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of novel, acyclic pyrrole-based anion receptors is described that bind nitrite and carboxylate anions with good selectivity in dichloroethane solution. These systems, which are based on pyridine 2,6-dicarboxamides, also bind cyanide anions weakly. Control systems, incorporating a benzene-1,3-dicarboxamide spacer or wherein the connectivity of the amide linkage is "reversed'', either failed to act as effective anion receptors or displayed very different selectivities.
引用
收藏
页码：646 / 654
页数：9
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