Estimation of the relative thickness of gas-diffusion electrodes of carbon-black blends in the course of electrosynthesis of the peroxide ion from oxygen

被引：2

作者：

Saltykov, YV ^{[1
]}

Kornienko, GV ^{[1
]}

Kenova, TA ^{[1
]}

Kornienko, VL ^{[1
]}

机构：

[1] Russian Acad Sci, Siberian Div, Inst Chem & Chem Technol, Krasnoyarsk, Russia

来源：

RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2000年 / 36卷 / 12期

关键词：

Oxygen; Hydrogen; Physical Chemistry; Peroxide; Furnace;

D O I：

10.1023/A:1026659932236

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The results of a study of electrosynthesis of hydrogen peroxide from oxy en in an alkaline electrolyte on gas-diffusion electrodes of acetylene carbon black and blends of acetylene carbon black and furnace black are compared. The relative thickness of gas-diffusion hydrophobic electrodes operating under inner-kinetic conditions is estimated from polarization curves. Improving the hydrogen peroxide removal from pores of the gas-diffusion electrodes made of carbon black blends with various hydrophilic and hydrophobic propel ties stabilizes the relative thickness of the electrodes in comparison with the electrodes of acetylene carbon black.

引用

页码：1314 / 1317

页数：4

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