Highly efficient Suzuki-Miyaura coupling reactions catalyzed by bis(oxazolinyl)phenyl-Pd(II) complex

被引：59

作者：

Takemoto, Toshihide

Iwasa, Seiji ^{[1
]}

Hamada, Hiroshi

Shibatomi, Kazutaka

Kameyama, Masayuki

Motoyama, Yukihiro

Nishiyama, Hisao

机构：

[1] Toyohashi Univ Technol, Dept Mat Sci, Toyohashi, Aichi 4418580, Japan

[2] Oyama Natl Coll Med, Dept Mat Chem & Bioengn, Oyama, Tochigi 3230806, Japan

[3] Kyushu Univ, Inst Mat Chem & Engn, Div Appl Chem, Res Sect Cluster Chem, Kasuga, Fukuoka 8168580, Japan

[4] Nagoya Univ, Dept Appl Chem, Grad Sch Engn, Nagoya, Aichi 464860, Japan

来源：

TETRAHEDRON LETTERS | 2007年 / 48卷 / 19期

关键词：

D O I：

10.1016/j.tetlet.2007.03.063

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Bis(oxazolinyl)phenyl-palladiui-n(II)(Phebox-Pd) complexes were found to be efficient catalysts for Suzuki-Miyaura coupling reactions of aryl boronic acids and their derivatives with aryl halides to give the corresponding biaryl products in high yield along with moderate enantioslectivities in the case of axially chiral induction. The catalytic activity was attained more than 900,000 of TON and 45,000 of TOF. The catalyst can be recovered quantitatively and could be reused for Suzuki-Miyaura reactions. (c) 2007 Elsevier Ltd. All rights reserved.

引用

页码：3397 / 3401

页数：5

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