An efficient Pd(II)-(2-aminonicotinaldehyde) complex as complementary catalyst for the Suzuki-Miyaura coupling in water

被引：12

作者：

Thung, Sanjeeva ^{[1
]}

Poshala, Soumya ^{[1
]}

Anugu, Naveenkumar ^{[1
]}

Konakanchi, Ramaiah ^{[1
]}

Vanaparthi, Satheesh ^{[1
,2
]}

Kokatla, Hari Prasad ^{[1
]}

机构：

[1] Natl Inst Technol Warangal, Dept Chem, Hanamkonda 506004, Telangana, India

[2] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, Assam, India

来源：

TETRAHEDRON LETTERS | 2019年 / 60卷 / 31期

关键词：

Suzuki-Miyaura coupling; Pd(II)-ANA catalyst; Water chemistry; Low catalyst loading; CARBON BOND FORMATION; C-C; PALLADIUM COMPLEXES; GRIGNARD-REAGENTS; ARYL; LIGANDS; HALIDES; NANOPARTICLES; CYTOTOXICITY; REACTIVITY;

D O I：

10.1016/j.tetlet.2019.06.051

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient new Pd(II)-(2-aminonicotinaldehyde)-catalyzed Suzuki-Miyaura coupling of the aryl halides (Br, Cl and I) and organoboronic acids at moderate temperature in water is described. Low catalyst loading, easy accessibility, being an air-stable catalyst, functional group compatibility, and water as the reaction medium are some of the key features of this synthetic method. This protocol is also applicable for gram scale. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页码：2046 / 2048

页数：3

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