Synthesis and physicochemical studies of cobalt(II), nickel(II) and copper(II) complexes with various Schiff bases containing oxygen and nitrogen donor atoms

被引:0
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作者
Dubey, Raj Kumar [1 ]
Mishra, Sharad Kumar [1 ]
Jha, Ashok Kumar [2 ]
Kumar, Manoj [1 ]
机构
[1] Univ Allahabad, Synthet Inorgan & Metalloorgan Res Lab, Dept Chem, Allahabad 211002, Uttar Pradesh, India
[2] TM Bhagalpur Univ, GB Coll, Dept Chem, Naugachia 853204, Bihar, India
关键词
Schiff base; IR; ESR; thermogravimetric analysis; SPECTRAL CHARACTERIZATION; LIGAND; SALICYLALDEHYDE; REACTIVITY; IR; MS;
D O I
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The complexes of cobalt(II), nickel(II) and copper(II) of the types [(sb)(2)M.2H(2)O] [where M = Co-II, Ni-II and Cu-II], [sbH = sapH, napH], [(CI)Cu(sb)] and [Cu(sb)(2)] [sb = sapH, smabH] have been prepared by using simple metathetic reactions. The structural characterization of the complexes, synthesized during the present course of investigations have been elucidated by elemental analysis (C, H, N, CI and Cu), IR, electronic spectral data, ESR, FAB-MS and magnetic studies. Thermogravimetric studies have also been carried out for some of the hydrated metal complexes.
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页码:527 / 532
页数:6
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