A crossed-beam study of the reaction C(1D)+H2(X1Σ+,υ=0)→CH(X2Π,υ′)+H(2S)

被引：66
|
作者：
Bergeat, A
Cartechini, L
Balucani, N
Capozza, G
Phillips, LF
Casavecchia, P [1 ]
Volpi, GG
Bonnet, L
Rayez, JC
机构：
[1] Dipartimento Chim, I-06123 Perugia, Italy
[2] Univ Bordeaux 1, Lab Physicochim Mol, F-33405 Talence, France
[3] Univ Bordeaux 1, Dept Mesures Phys, IUT A, F-33405 Talence, France
来源：
CHEMICAL PHYSICS LETTERS | 2000年 / 327卷 / 3-4期
关键词：
D O I：
10.1016/S0009-2614(00)00870-8
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Product angular and time-of-flight distributions have been measured for the first time for the prototypical insertion reaction C(D-1) + H-2 using the crossed-beam technique with mass spectrometric detection at the collision energy of 1.86 kcal mol(-1). Center-of-mass angular and kinetic energy distributions have been derived for CH(X(2)Pi, nu', = 0) + H products and compared with those of statistical calculations based on phase-space theory. (C) 2000 Elsevier Science B.V. All rights reserved.
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页码：197 / 202
页数：6
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