Aldol condensation of acetone in an undivided cell via electrochemical catalyzed reaction

被引：0
|
作者：
Tsai, ML [1 ]
Chou, TC [1 ]
机构：
[1] Natl Cheng Kung Univ, Dept Chem Engn, Tainan 70101, Taiwan
来源：
JOURNAL OF THE CHINESE INSTITUTE OF CHEMICAL ENGINEERS | 1997年 / 28卷 / 06期
关键词：
undivided cell; aldol condensation;
D O I：
暂无
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Aldol condensation of acetone was explored in the undivided cell by electrolysis. The results revealed that the yield of diacetone alcohol was mainly affected by the types of electrolyte, concentration of acetone and reaction temperature. On the other hand, electricity passed, current density and concentration of KCl were the minor factors. At the optimum condition, the yield of diacetone alcohol was 1150 g-F-1. In the absence of solvent, the formation rate of diacetone alcohol by using a graphite as anode material is faster than that of Pt anode.
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页码：381 / 387
页数：7
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