Synthesis and complexation properties towards metal ions of new tri-substituted thiacalix[4]arenes

被引：0
|
作者：
Ben Maamar, Sami [2 ,4 ]
Jadambaa, Natsagma [2 ]
Vocanson, Francis [3 ]
Meganem, Faouzi [4 ]
Felix, Caroline [1 ]
Dumazet-Bonnamour, Isabelle [1 ]
机构：
[1] Univ Lyon 1, UFR Chim, F-69622 Villeurbanne, France
[2] Univ Lyon, Lyon, France
[3] Univ St Etienne, St Etienne, France
[4] Fac Sci Bizerte, Jarzouna, Bizerte, Tunisia
来源：
SUPRAMOLECULAR CHEMISTRY | 2009年 / 21卷 / 06期
关键词：
thiacalix[4]arene; synthesis; conformation; metal complexation; EXTRACTION;
D O I：
10.1080/10610270802195586
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New thiacalix[4]arenes appended with three amide functions have been prepared. Their conformations have been solved thanks to 1H NMR 2D correlation spectroscopy (COSY) and nuclear overhauser and exchange spectroscopy (NOESY). The complexation ability of these ligands towards various metal ions (Cd2+, Pb2+, Pd2+, Ni2+, Hg2+, Hg+, Ag+, Zn2+ and Cu2+) has been investigated by the UV-vis absorption and the stoichiometry of the metal-ligand complexes was determined.
引用
收藏
页码：450 / 454
页数：5
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