Inverted N-confused porphyrin dimer

被引：48
|
作者：
Ishizuka, T
Osuka, A
Furuta, H [1 ]
机构：
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Fukuoka 8128581, Japan
[2] Kyoto Univ, Grad Sch Sci, Dept Chem, Kyoto 6068502, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 38期
关键词：
aromaticity; macrocyclic ligands; N ligands; N-confused porphyrins; porphyrinoids;
D O I：
10.1002/anie.200460017
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A covalently linked N-fused porphyrin dimer was synthesized by treatment of the monomer with Ag(OCOCF3). Subsequent reaction of this dimer with NaOMe led to a porphyrin dimer with two α,β-bound ("confused") pyrrole rings (see scheme) which adopt the inverted conformation. The dimer exhibits aromaticity in spite of its highly distorted structure.
引用
收藏
页码：5077 / 5081
页数：5
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