One-step reaction of Friedel-Crafts acylation and demethylation of aryl-methyl ethers catalyzed by ytterbium(III) triflate

被引:8
|
作者
Su, WK [1 ]
Jin, C [1 ]
机构
[1] Zhejiang Univ Technol, Coll Pharmaceut Sci, Hangzhou 310014, Peoples R China
基金
中国国家自然科学基金;
关键词
demethylation; ethers; Friedel-Crafts acylation; ytterbium(III) triflate;
D O I
10.1081/SCC-200036628
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Catalytic amount of ytterbium(III) triflate [Yb(OTf)(3)] has been used to catalyze Friedel-Crafts acylation and demethylation of aryl-methyl ethers in one-step reaction to produce hydroxyacylphenones with moderate yields under mild conditions.
引用
收藏
页码:4199 / 4205
页数:7
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