Synthesis of sulfur containing macrocycles with sucrose scaffold

被引：2

作者：

Gajewska, Agnieszka ^{[1
,2
]}

Osuch-Kwiatkowska, Anna ^{[1
]}

Jarosz, Slawomir ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland

[2] PAS, Inst Phys Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland

来源：

CARBOHYDRATE RESEARCH | 2019年 / 486卷

关键词：

Sucrose; Sulfur macrocycles; Cyclization; DERIVATIVES;

D O I：

10.1016/j.carres.2019.107825

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The first synthesis of sucrose-based macrocycles containing two sulfur atoms in the ring was presented. The synthesis was initiated from known 6,6'-dideoxy-6,6'-di-chloro-1',2,3,3',4,4'-hexa-O-benzyl-sucrose in which both terminal positions (C6 and C6') were elongated by the -S-CH2-CH2-OH unit. The resulting diol was converted into dichloride and reacted further with a series of diamines which afforded the corresponding macrocyclic derivatives in high yields.

引用

页数：5

共 50 条

[21] Synthesis of Spiroligomer-Containing Macrocycles
Zhao, Qingquan
Schafmeister, Christian E.
JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (18): : 8968 - 8978
[22] Synthesis and cellular uptake properties of guanidine-containing molecular transporters built on the sucrose scaffold
Lee, Woo Sirl
Im, Chang-Nim
Teng, Qi Ying
Chang, Young-Tae
Kim, Dong-Chan
Kim, Kyong-Tae
Chung, Sung-Kee
MOLECULAR BIOSYSTEMS, 2009, 5 (08) : 822 - 825
[23] Synthesis of new phosphorus containing macrocycles
Bauer, I
Habicher, WD
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1997, 130 : 89 - 105
[24] INOR 190-Synthesis and characterization of novel macrocycles containing nitrogen, oxygen, and sulfur donor atoms
Hugdahl, Jeffrey
Brill, Matthew
Klausmeyer, Kevin K.
Dopke, Joel A.
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 232
[25] SYNTHESIS AND CHARACTERIZATION OF OXYGEN AND SULFUR BRIDGED AROMATIC MACROCYCLES
BOTTINO, F
FOTI, S
PAPPALARDO, S
TETRAHEDRON, 1976, 32 (21) : 2567 - 2570
[26] Synthesis of nitrogen and sulfur macrocycles with cis exogenous oxygen and sulfur donor atoms
White, VA
Long, NJ
Robertson, N
ORGANIC & BIOMOLECULAR CHEMISTRY, 2005, 3 (23) : 4268 - 4273
[27] Synthesis and characterization of squaraine-containing macrocycles
Pantano, Justin
Levine, Mindy
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2019, 258
[28] SYNTHESIS AND COMPLEXABILITY OF PHOSPHORUS-CONTAINING MACROCYCLES
TSVETKOV, EN
BOVIN, AN
SYUNDYUKOVA, VK
USPEKHI KHIMII, 1988, 57 (08) : 1353 - 1402
[29] SYNTHESIS OF PHOSPHORUS-CONTAINING MACROCYCLES AND CRYPTANDS
CAMINADE, AM
MAJORAL, JP
CHEMICAL REVIEWS, 1994, 94 (05) : 1183 - 1213
[30] SYNTHESIS OF MACROCYCLES, CONTAINING THIOPHENE AND THIAZOLE RINGS
GOLDFARB, YL
KRASNYANSKAYA, EA
DUDINOV, AA
TAITS, SZ
KHIMIYA GETEROTSIKLICHESKIKH SOEDINENII, 1986, (06): : 841 - 844

← 1 2 3 4 5 →