Synthesis of sulfur containing macrocycles with sucrose scaffold

被引：2

作者：

Gajewska, Agnieszka ^{[1
,2
]}

Osuch-Kwiatkowska, Anna ^{[1
]}

Jarosz, Slawomir ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland

[2] PAS, Inst Phys Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland

来源：

CARBOHYDRATE RESEARCH | 2019年 / 486卷

关键词：

Sucrose; Sulfur macrocycles; Cyclization; DERIVATIVES;

D O I：

10.1016/j.carres.2019.107825

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The first synthesis of sucrose-based macrocycles containing two sulfur atoms in the ring was presented. The synthesis was initiated from known 6,6'-dideoxy-6,6'-di-chloro-1',2,3,3',4,4'-hexa-O-benzyl-sucrose in which both terminal positions (C6 and C6') were elongated by the -S-CH2-CH2-OH unit. The resulting diol was converted into dichloride and reacted further with a series of diamines which afforded the corresponding macrocyclic derivatives in high yields.

引用

页数：5

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