Heterocycles as corrosion inhibitors for zinc pigments in aqueous alkaline media

被引:25
|
作者
Muller, B
Imblo, G
机构
[1] Fachhochschule fuer Druck Stuttgart, Germany
关键词
aluminium; zinc;
D O I
10.1016/0010-938X(96)00122-9
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Zinc pigments react in aqueous alkaline media (e.g. water-borne paints) by the evolution of hydrogen. Heterocyclic compounds can inhibit this corrosion reaction. The corrosion inhibiting effect of the heterocycles depends strongly on the base which is used for adjusting the pH value to 10. Ammonia accelerates the corrosion reaction very much; the protection factors for the heterocycles are 5-40%. The examined heterocycles inhibit significantly better if dimethylethanolamine or sodium hydroxide are used as bases; protection factors increase up to 98%. The corrosion inhibiting effect of heterocycles can be explained by reference to Pearson [R.G.Pearson, J. Chem. Ed, 45, 581 (1968)]
引用
收藏
页码:293 / 300
页数:8
相关论文
共 50 条
  • [41] Inhibition efficiencies of some organic compounds on the corrosion of zinc in alkaline media
    Bereket, G
    Gülec, M
    Yurt, A
    ANTI-CORROSION METHODS AND MATERIALS, 2006, 53 (01) : 52 - 56
  • [42] Carboxylic acids as efficient corrosion inhibitors of aluminium alloys in alkaline media
    Wysocka, Joanna
    Cieslik, Mateusz
    Krakowiak, Stefan
    Ryl, Jacek
    ELECTROCHIMICA ACTA, 2018, 289 : 175 - 192
  • [43] Aluminum pigments encapsulated by inorganic–organic hybrid coatings and their stability in alkaline aqueous media
    Li-Jun Li
    Pi-Hui Pi
    Xiu-Fang Wen
    Jiang Cheng
    Zhuo-Ru Yang
    Journal of Coatings Technology and Research, 2008, 5 : 77 - 83
  • [44] Corrosion protection with modified zinc pigments
    Wanner, Matthias
    Mba, Michael Hilt
    Aktas, Lukas
    Galvanotechnik, 2020, 111 (12): : 1796 - 1801
  • [45] CORROSION INHIBITION RESP STIMULATION OF ALUMINUM PIGMENTS IN AQUEOUS ALKALINE-MEDIUM BY POLYACRYLIC ACIDS
    MULLER, B
    SCHMELICH, T
    WERKSTOFFE UND KORROSION-MATERIALS AND CORROSION, 1994, 45 (12): : 637 - 640
  • [46] Electrochemical and surface studies of zinc in alkaline solutions containing organic corrosion inhibitors
    Ein-Eli, Y
    Auinat, M
    Starosvetsky, D
    JOURNAL OF POWER SOURCES, 2003, 114 (02) : 330 - 337
  • [47] The effect of some organic surfactants on the corrosion of zinc in neutral and alkaline aqueous solutions
    Branzoi, Viorel
    Pruna, Lina
    Branzoi, Florina
    REVUE ROUMAINE DE CHIMIE, 2007, 52 (06) : 587 - 595
  • [48] CORROSION INHIBITORS FOR ZINC
    DESAI, MN
    RANA, SS
    GANDHI, MH
    ANTI-CORROSION METHODS AND MATERIALS, 1973, 20 (12) : 3 - 6
  • [49] Some Organic Additives as Corrosion Inhibitors for Zinc in Acetic Acid Media
    El-Aila, Hisham J.
    Tamouse, Hassan M.
    Amin, Nabil H.
    El-Jboour, Mohamed A.
    JORDAN JOURNAL OF CHEMISTRY, 2011, 6 (03) : 321 - 337
  • [50] Some Natural Additives as Corrosion Inhibitors for Zinc in Acetic Acid Media
    El-Aila, H. J. Y.
    Amin, N. H.
    Tamouse, H. M.
    El-Jboour, M. A.
    JORDAN JOURNAL OF CHEMISTRY, 2010, 5 (01) : 59 - 73