Evaluation of multiple melting peaks of propylene-ethylene copolymers

被引:25
|
作者
Feng, YD [1 ]
Jin, XR [1 ]
Hay, JN [1 ]
机构
[1] Univ Birmingham, Sch Met & Mat, Birmingham B15 2TT, W Midlands, England
关键词
multiple melting peaks; propylene-ethylene copolymers; recrystallization; compositional heterogeneity;
D O I
10.1295/polymj.30.215
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Multiple melting peaks phenomena have been investigated in terms of compositional heterogeneity, crystallization temperature, cooling rate, heating rate, annealing and crystal structure for low ethylene content block and random propylene-ethylene copolymers. The experimental results suggested that the compositional heterogeneity and crystal morphology play an important role in the cause of multiple melting behavior.
引用
收藏
页码:215 / 221
页数:7
相关论文
共 50 条
  • [31] Propylene-ethylene copolymers by one-monomer metallocene catalyzed polymerization
    Dias, ML
    Lopes, DEB
    Grafov, AV
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 185 (1-2) : 57 - 64
  • [32] Fractionation and characterisation of propylene-ethylene random copolymers:: Effect of the comonomer on crystallisation of poly(propylene) in the γ-phase
    Harding, Gareth W.
    van Reenen, Albert J.
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2006, 207 (18) : 1680 - 1690
  • [33] Effect of crystallization temperature and propylene sequence length on the crystalline structure of propylene-ethylene random copolymers
    GOU QingQiang1
    2 Department of Polymer Science
    3 Beijing Research Institute of Chemical Industry
    Chinese Science Bulletin, 2008, (12) : 1804 - 1812
  • [34] Solubility and Diffusivity of Propylene, Ethylene, and Propylene-Ethylene Mixtures in Polypropylene
    Cancelas, Aaron J.
    Plata, Miguel A.
    Bashir, Muhammad Ahsan
    Bartke, Michael
    Monteil, Vincent
    McKenna, Timothy F. L.
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2018, 219 (08)
  • [35] Effect of crystallization temperature and propylene sequence length on the crystalline structure of propylene-ethylene random copolymers
    Gou QingQiang
    Li HuiHui
    Yu ZhenQiang
    Chen ErQiang
    Zhang YuDong
    Yan ShouKe
    CHINESE SCIENCE BULLETIN, 2008, 53 (12): : 1804 - 1812
  • [36] The cocrystallization behavior of binary blends of isotactic polypropylene and propylene-ethylene random copolymers
    Kim, MH
    Alamo, RG
    Lin, JS
    POLYMER ENGINEERING AND SCIENCE, 1999, 39 (11): : 2117 - 2131
  • [37] Incorporation of low viscosity amorphous propylene-ethylene copolymers in adhesive and sealant formulations
    Miller, RA
    1998 HOT MELT SYMPOSIUM, 1998, : 119 - 127
  • [38] Compositional differences of propylene-ethylene block copolymers manufactured by degradation and hydrogenation techniques
    Zhang, Chuanzhi
    Yu, Fusheng
    Wang, Li-Qun
    Tu, Kehua
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 101 (05) : 3301 - 3306
  • [39] Structure-properties of new propylene-ethylene (P/E) copolymers.
    Bosnyak, CP
    Bar, G
    Li, J
    Chang, A
    Ansems, P
    Chum, S
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U521 - U521
  • [40] Effect of melt annealing on the phase structure and rheological behavior of propylene-ethylene copolymers
    De La Torre, Vanesa
    Fris, Jorge A. Rodriguez
    Failla, Marcelo D.
    Quinzani, Lidia M.
    POLYMER ENGINEERING AND SCIENCE, 2007, 47 (06): : 912 - 921